Product ID:BLU-RAM HS, 5039
MSDS Date:05/01/1990
FSC:9330
NIIN:00N073027
MSDS Number: CBZLH

PREMIER REFRACTORIES & CHEMICALS INC

901 EAST EIGHTH AVE
KING OF PRUSSIA, PA 19406
US

Emergency Phone: 215-337-1100

Info Phone: 215-337-1100

Preparer: AG NIGHSWANDER

Cage: PREMI

PREMIER REFRACTORIES AND CHEMICALS INC

1569 KING OF PRUSSIA, PA 19406 US

Telephone: 215-337-1100

Cage: PREMI

3); (ALUMINA) (SARA 313)

CAS: 1344-28-1

RTECS: BD1200000

Fraction By Weight: 10-40%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

ALUMINUM SILICATE; (ALUMINOSILICATE)

CAS: 1302-93-8

Fraction By Weight: 30-70%

OSHA PEL N/K

ACGIH TLV: N/K

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

TRIALUMINUM PHOSPHATE; (ALUMINUM PHOSPHATE)

CAS: 13530-50-2

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORIC ACID (SARA 313) (CERCLA)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 0.5-1%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICA, CRYSTALLINE - CRISTOBALITE; (CRISTOBALITE)

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 0-0.2%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.05 MG/M3 RDUST

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 0-0.2%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

SILICA, CRYSTALLINE - FUSED; (SILICA, FUSED)

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 1-10%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

CLAY

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

COPPER, (PHTHALOCYANINATO(2-))-; (BLUE DYE)

CAS: 147-14-8

RTECS: GL8510000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

SUPPRESSION & CTL IS IMPERATIVE. FOLLOWING ARE

RTECS: 9999999ZZ

BE APPRISED OF THE HAZ & PROPER CNDTNS & PREC FOR

RTECS: 9999999ZZ

29 CFR 1910.134, SHOULD BE USED FOR DUST LEVELS

RTECS: 9999999ZZ

GENERATION SHOULD BE MINIMIZED BY USE OF DUST CTL

RTECS: 9999999ZZ

PRIOR TO REMOVING CLTHG. 5. WHERE THERE IS A

RTECS: 9999999ZZ

SILICA, THE FOLLOWING WARNING SHOULD BE POSTED

RTECS: 9999999ZZ

DELAYED LUNG INJURY (SILICOSIS).

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THIS PROD IN ITS CURRENT STATE IS A
MOIST, MOLDABLE MATL. PHOSPHORIC ACID IN PROD IS CORR TO EYES &
SKIN. SOME OF THE HLTH HAZ INFO ALSO APPLIES TO DRIED MATL & ANY
DUST THAT MAY RSLT THEREFROM. TARGE T ORGANS: EYES & SKIN, & RESP
TRACT IF DUST IS PRESENT. ACUTE: EYE: PHYSICAL IRRIT &/BURNING
SENSATION (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE;
SILICA, CRYSTALLINE-QUARTZ, & SILICA, CRYSTALLINE-FUSED: IARC MONO,
SUPP, (SUP DAT)
Effects of Overexposure:HLTH HAZ: FROM PHOSPHORIC ACID. SKIN: IRRIT
&/INFLAMM FROM SKIN CONT. INHAL: BRTHG DFCLTYS. CHRONIC: EXCESS
INHAL ABOVE PEL OF CRYSTALLINE SILICA (FREE SILICA), OVER LONG
PERIODS OF TIME, MAY CAUSE DI SABLING LUNG DISEASE (SILICOSIS)
WHICH REDUCES BRTHG CAPACITY, & LEAD TO INCRD SUSCEPTIBILITY TO
OTHER LUNG DISEASE.
Medical Cond Aggravated by Exposure:PREEXISTING CHRONIC LUNG CONDITIONS
SUCH AS, BUT NOT LIMITED TO, BRONCHITIS, EMPHYSEMA, AND ASTHMA FROM
DUST.

First Aid:EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP
AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: CALL MD
IMMEDIATE LY .

Extinguishing Media:THIS REFRACTORY PRODUCT IS NON-COMBUSTIBLE. USE
EXTINGUISHING MEDIA APPROPRIATE TO THE SURROUNDING AREA.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:SPILLS SHOULD BE CLEANED UP TO AVOID SLIPPING.
CAREFULLY SCOOP UP MATL INTO SUITABLE CONTR. FLUSH AREA W/COPIOUS
AMTS OF WATER. CLEAN-UP PERS SHOULD WEAR NIOSH APPRVD RESP PROT,
GLOVES & GOGG TO PVNT IRRIT FROM CONT AND/OR INHALATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:REMOVAL AFTER SERVICE PREC: BECAUSE OF THE POSS
PRESENCE OF CRYSTALLINE SILICA IN USED REFRACTORY LININGS,
PARTICULAR CARE SHOULD BE EXERCISED DURING TEAR-OUT TO MINIMIZE
GENERATION OF DUST. ADHERANCE TO PROPER METHODS OF DUST (ING 11)

Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:PROVIDE ADEQUATE GENERAL VENTILATION AND LOCAL VENTILATION
TO CONTROL MIST AND DUST LEVELS TO NO MORE THAN THE TLV.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . USE OF LONG SLEEVE CLOTHING IS RECOMMENDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MP: >2732F, >1500C. PH: 2.5-3.5 (10% AQUEOUS SLURRY). APPEAR & ODOR:
MUD. PROD HAS A SLIGHT PUNGENT ODOR. EXPLAN OF CARCIN: VOL 7, PG
341, 1987: GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO
BE CARCIN. ANIMAL: LUNG.

Melt/Freeze Pt:M.P/F.P Text:SUP DAT
Spec Gravity:2.8-2.9(H*2O=1)
pH:SUPDAT
Solubility in Water:3-5%
Appearance and Odor:BLUE MIX OF AGGREGATES & MOIST BONDING MATLS
W/CONSISTENCY OF STIFF (SUP DAT)
Percent Volatiles by Volume:1-2

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:TO AVOID DRYOUT, MATERIAL SHOULD BE STORED
IN MOISTURE-PROOF PLASTIC-LINED CONTAINERS.
Hazardous Decomposition Products:NONE.

Waste Disposal Methods:PRODUCT IS NON-BIODEGRADABLE, AND DOES NOT
POSSESS CHARACTERISTICS OF A HAZARDOUS WASTE PER EPA METHODS.
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.